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Muataz in Catal Lett (2014)
Selective Acetalization of Glycerol with Acetone Over Nickel Nanoparticles Supported on Multi-Walled Carbon Nanotubes
Catalysis Letter in Press
M. S. Khayoon • A. Abbas • B. H. Hameed •, S. Triwahyono • A. A. Jalil • A. T. Harris • A. I. Minett 
 
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ABSTRACT  
The use of multi-walled carbon nanotubes for catalytic applications is acquiring great interest. In this work, heterogeneous catalysts were prepared by incorporating nickel nanoparticles into MWCNTs and were characterized by BET, surface acidity, FTIR, XRD, Raman spectroscopy, and TEM analysis. The Ni-containing catalysts have presented unique catalytic performance in the selective formation of glycerol ketal and acetal via the solventless acetalization with acetone. The formation of glycerol acetal via glycerol ketalization with acetone can be considered as one of the earlier attempts in this field. Experimental investigations revealed that at 40 C, Ni(1.8)/MWCNTs facilitated the conversion of 96 % glycerol with corresponding selectivity of 72 and 28 % toward ketal and acetal, respectively, within 3 h. The unique catalytic performance of this catalyst is mainly attributable to its high acidity and the structural characteristics. The stability of the catalytic activity was examined upon recycling the catalyst for four consecutive batch runs. 
 
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Applications are invited for a PhD/Master student to work in the design and synthesis of solid acid-base catalyst, photocatalyst or adsorbent. Applicants should have at least a 2nd UPPER degree in Chemistry or Chemical Engineering. The posts are available immediately. All inquiries and applications (with your detail CV for our reference) to : 

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2014 PUBLICATION
  1. Role of mesostructure silica naanoparticle in forming alpha-FeOOH-ionic liquid micelle for enhanced photocatalytic, under revision in JCIS
  2. Effect of Cr/Zr ratio in the cumene conversion over modified CN-CZ, under review
  3. Catalytic valorization of carbon dioxide to methane over MSN-supported metal catalysts (arif02), submitted
  4. Mercury (II) removal from aqueous solution using celullose (dayah01), submitted
  5. Cr removal from aqueous solution using mesoprous material (dayah), submitted
  6. Effect Si/Al ratio in the cumene conversion over modified MSN catalyst (reza02), will be submitted soon 
  7. M.A.A. Aziz, A.A. Jalil, S. Triwahyono*, R.R. Mukti, Y.H. Taufiq-Yap, M.R. Sazegar, Highly active Ni promoted mesostructured silica nanoparticles for CO2 methanation, Applied Catalysis B : Environmental 147(2014)259-368. (IF5.825). |pdf|
  8. M.R. Sazegar, A.A. Jalil, S. Triwahyono*, R.R. Mukti, M. Aziz, M.A.A. Aziz, H.D. Setiabudi, N.H.N. Kamarudin, Protonation of Al-grafted Mesostructured Silica Nanoparticles (MSN): Acidity and Catalytic Activity for Cumene Hydrocracking, Chemical Engineering Journal  240(2014)352-361. (IF3.473). |pdf|
  9. M.S. Khayoon, S. Triwahyono*, B.H. Hameed and A.A. Jalil, Catalytic esterification of glycerol with acetic acid over Yttrium containing catalyst: The selective synthesis of fuel additives, Chemical Engineering Journal 243(2014)473-484.  (IF3.473). |pdf|
  10. R. Jusoh, A.A. Jalil*, S. Triwahyono, A. Idris, S. Haron, N. Sapawe, N.F. Jaafar, N.W.C. Jusoh, Synthesis of reverse micelle <alpha>-FeOOH nanoparticles in ionic liquid as an only electrolyte: Inhibition of electron-hole pair recombination for efficient photoactivity, Applied Catalysis A : General  469(2014)33-44. (IF3.410). |pdf|
  11. N.H.N. Kamarudin, A.A. Jalil*, S. Triwahyono, V. Artika, N.F.M. Salleh, A.H. Karim, N.F. Jaafar, M.R. Sazegar, R.R. Mukti, B.H. Hameed, A. Johari, Variation of the crystal growth of mesoporous silica nanoparticles and the evaluation to ibuprofen loading and release, Journal of Colloid and Interface Science 421(2014)6-13 (IF3.172). |pdf|
  12. A.H. Karim, A.A. Jalil*, S. Triwahyono, N.H.N. Kamarudin, A. Ripin, Influence of multi-walled carbon nanotubes on textural and adsorption characteristics of in situ synthesized mesostructured silicaJournal of Colloid and Interface Science 421(2014)93-102. (IF3.172). |pdf|
  13. N.H.R.  Annuar, S. Triwahyono*, A.A. Jalil, N.A.A.  Fatah, L.P.  Teh, C.R. Mamat, Effect of chromium precursor on the properties of chromium oxide zirconia, Applied Catalysis A : General  475(2014)487-496 (IF3.410). |pdf| 
  14. M. S. Khayoon, A. Abbas, B. H. Hameed, S. Triwahyono*, A. A. Jalil, A. T. Harris, A. I. Minett, Selective acetalization of glycerol with acetone over Nickel nanoparticles supported on multi-walled carbon nanotubes, ACCEPTED in Catalysis Letters (IF2.244). |pdf|  
  15. Carbon dioxide reforming over mesoporous materials (mun01), will be submitted soon 
  16. As (III) removal from aqueous solution using celullose (chee01), will be submitted soon 
  17. Biodiesel production over silica based catalyst (khalida01). will be submitted 
  18. Optimization of CO2 Methanation over MSN based catalyst (arif03), will be submitted 
  19. Heptane isomerization over TON catalyst, will be submitted
  20. Study of interaction between cumene and MoO3 type catalyst: Optimization of cumene hydrocracking by RSM (jiha03), will be submitted
  21. Heptane isomerization over MSN based catalyst, will be submitted
  22. Lower alkane isomerization over modified zeolite material, will be submitted

 
2013 PUBLICATION
  1. N.W.C. Jusoh, A.A. Jalil*, S. Triwahyono, H.D. Setiabudi, N. Sapawe, M.A.H. Satar, A.H. Karim, N.H.N. Kamarudin, R. Jusoh, N.F. Jaafar, N. Salamun, J. Efendi, Sequential desilication-isomorphous substitution route to preparing Mesostructured Silica Nanoparticles loaded with ZnO and their photocatalytic activity, Applied Catalysis A : General  468(2013)276-287 (IF3.410)|pdf|
  2. N. Sapawe, A.A. Jalil*, S. Triwahyono, M.I.A. Shah, R. Jusoh, N.F.M. Salleh, and B.H. Hameed, Cost–effective microwave rapid synthesis of zeolite NaA for removal of methylene blue, Chemical Engineering Journal 229 (2013) 388-389 (IF3.473). |pdf|
  3. N.H.N. Kamarudin, A.A. Jalil*, S. Triwahyono, N.F.M. Salleh, A.H. Karim, R.R. Mukti, and B.H. Hameed, Role of 3-aminopropyltriethoxysilane in the preparation of mesoporous silica nanoparticles for ibuprofen delivery: Effect on physicochemical properties, Microporous and Mesoporous Materials 180 (2013) 235-241. (IF3.365). |pdf|
  4. S. Triwahyono*, A.A. Jalil, N.N. Ruslan, H.D. Setiabudi, N.H.N.  Kamarudin, "C5-C7 linear alkane hydroisomerization over MoO3-ZrO2 and Pt/MoO3-ZrO2 catalysts", Journal of Catalysis  303(2013)50–59 (IF5.787). |pdf|
  5. S.N. Timmiati, A.A  Jalil, S. Triwahyono*, H.D.  Setiabudi, N.H.R.  Annuar, "Formation of acidic Brönsted (MoOx)-(Hy)+ evidenced by XRD and 2,6-lutidine FTIR Spectroscopy for cumene cracking", Applied Catalysis A : General  459(2013)8-16 (IF3.410). |pdf|
  6. N. Sapawe, A. A. Jalil*, S. Triwahyono, R.N. R.A. Sah, N.W. C. Jusoh, N.H.H. Hairom, J.Efendi, "Electrochemical strategy for grown ZnO nanoparticles deposited onto HY zeolite with enhanced photodecolorization of methylene blue: Effect of the formation of Si-O-Zn bonds", Applied Catalysis A : General 456(2013)144-158. (IF3.410). |pdf|
  7. H.D. Setiabudi, A.A. Jalil, S. Triwahyono*, "Ir/Pt-HZSM5 for n-pentane isomerization: Effect of Si/Al ratio and reaction optimization by response surface methodology",Chemical Engineering Journal 217(2013)300-309. (IF3.473). |pdf|
  8. N. Sapawe, A. A. Jalil*, S. Triwahyono, "One-pot electro-synthesis of ZrO2-ZnO/HY nanocomposite for photocatalytic decolorization of various dye-contaminants", Chemical Engineering Journal 225(2013)254–265 (IF3.473). |pdf|
  9. N.H.R. Annuar, A.A. Jalil, S. Triwahyono*Z. RamliRelating cumene hydrocracking activity to the acidic center of CrO3-ZrO2, Journal of Molecular Catalysis A: Chemical377(2013)162-172. (IF3.187). |pdf|
  10. A. A. Jalil*, M.A.H. Satar, S. Triwahyono, H.D. Setiabudi, N.H.N. Kamarudin, N.F. Jaafar, N. Sapawe, R. Ahamad, "Tailoring the current density to enhance photoactivity performance of electrosynthesized CuO/HY catalyst", Journal of Electroanalytical Chemistry 70(2013)50-58 (IF2.672). |pdf|
  11. P. V. Suraja, Z. Yaakob, N. N. Binitha, S. Triwahyono, P. P. Silija*, "Co3O4 doped over SBA 15: excellent adsorbent material for the removal of methyleneblue dye Pollutant", Clean Technologies and Environmental Policy  15(2013)967-975 (IF1.827). |pdf|
  12. Hartati, Mardi Santoso, Sugeng Triwahyono, Didik Prasetyoko*, Activities of Heterogeneous Acid-Base Catalysts for Fragrances Synthesis: A Review, Bulletin of Chemical Reaction Engineering and Catalysis 8(1)(2013)14-33 (IF0; Scopus). |pdf|
  13. M.A.A. Aziz, A.A. Jalil and S. Triwahyono*, Promotive Effect of Hydrogen in n-Hexane Isomerization over Ni/PtHY Catalyst, Malaysian Journal of Fundamental and Applied Sciences 9(4) (2013) 225-230. (IF0). |pdf|
  14. H.D. Setiabudi, A.A. Jalil, S. Triwahyono*, S.N. Timmiati, N.H.R. Annuar, N.A.A. Fatah, M.R. Sazegar, L.P. Teh ,Effect of iridium loading on the formation of protonic acid sites over Ir/Pt-HZSM5, Malaysian Journal of Fundamental and Applied Sciences  9(1)(2013)10-15. (IF0). |pdf|
  15. N. Sapawe, A.A. Jalil*, S. Triwahyono, Photodecolorization of methylene blue over EGZrO2/EGZnO/EGFe2O3/HY photocatalyst: Effect of radical scavenger, Malaysian Journal of Fundamental and Applied Sciences  9(2)(2013)67-73. (IF0). |pdf| 

 
Last Modified :Tuesday 15 April 2014, 18:36
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